Thermodynamics is concerned with the relationship between other forms of energy and heat. It explains how thermal energy is converted from other forms of energy. The energy coming from heat is termed thermal energy. When the tiny particles within an object move, they generate heat, more amount of heat is generated, when these particles move at a faster pace.
Laws of Thermodynamics: The laws of thermodynamics define the fundamental physical quantities like energy, temperature, and entropy that characterize thermodynamic systems at thermal equilibrium. The four laws of thermodynamics are:
Zeroth Law: It states that when two systems are in thermal equilibrium with the third system which is separate, the whole system together is said to be in equilibrium with one another.
First Law: It states the law of conservation of energy when applied to a system in which the energy transfer occurs from or towards the system (with the help of heat and work). It represents the relation between the work done by the system, heat supplied to the system and the change in the internal energy of the system.
Second Law: It states that it is not possible to find a system, where the absorption of heat from the reservoir is the complete conversion of heat into work.
Third Law: This law states that at an absolute zero temperature, the system posses minimum energy.
Enthalpy: In a thermodynamic setup, enthalpy is the measurement of energy. The quantity of enthalpy equals the total content of the heat of a system, equivalent to the system’s internal energy plus the product of volume and pressure.
Numerically, H (the enthalpy), equals the sum of E (the internal energy), and P (the product of the pressure), and V (volume) of the system.
H = E + PV
Entropy: Entropy's value depends on the physical state or condition of a system. It is a thermodynamic function that is utilized to measure the disorder or randomness of a system. For instance, the entropy of a solid, where particle movement is restricted, is less than the entropy of gas, wherein the particles occupy the container.